Effect of hydrogen limitation and temperature on the fractionation of sulfur isotopes by a deep-sea hydrothermal vent sulfate-reducing bacterium     

Joost Hoek  Anna-Louise Reysenbach  Donald E. Canfield 《Geochimica et cosmochimica acta》2006,70(23):5831-5841

The fractionation of sulfur isotopes by the thermophilic chemolithoautotrophic Thermodesulfatator indicus was explored during sulfate reduction under excess and reduced hydrogen supply, and the full temperature range of growth (40-80 °C). Fractionation of sulfur isotopes measured under reduced H₂ conditions in a fed-batch culture revealed high fractionations (24-37‰) compared to fractionations produced under excess H₂ supply (1-6‰). Higher fractionations correlated with lower sulfate reduction rates. Such high fractionations have never been reported for growth on H₂. For temperature-dependant fractionation experiments cell-specific rates of sulfate reduction increased with increasing temperatures to 70 °C after which sulfate-reduction rates rapidly decreased. Fractionations were relatively high at 40 °C and decreased with increasing temperature from 40-60 °C. Above 60 °C, fractionation trends switched and increased again with increasing temperatures. These temperature-dependant fractionation trends have not previously been reported for growth on H₂ and are not predicted by a generally accepted fractionation model for sulfate reduction, where fractionations are controlled as a function of temperature, by the balance of the exchange of sulfate across the cell membrane, and enzymatic reduction rates of sulfate. Our results are reproduced with a model where fractionation is controlled by differences in the temperature response of enzyme reaction rates and the exchange of sulfate in and out of the cell.  相似文献   

Correlations in aftershock and seismicity patterns     

Robert Shcherbakov  Jordan Van Aalsburg  John B. Rundle  Donald L. Turcotte   《Tectonophysics》2006,413(1-2):53

Correlations in space and time play a fundamental role in earthquake processes. One direct manifestation of the effects of correlations is the occurrence of aftershocks due to the stress transfer in the vicinity of a main shock. Less obvious and more speculative changes in correlations may occur in the background seismicity before large earthquakes. Using statistical physics it is possible to introduce a measure of spatial correlations through a correlation length. This quantity characterizes how local fluctuations can influence the occurrence of earthquakes over distances comparable with the correlation length. In this work, the physical basis of spatial correlations of earthquakes is discussed in the context of critical phenomena and the percolation problem. The method of two-point correlation function is applied to the seismicity of California. Well defined variations in time of the correlation length are found for aftershock sequences and background seismicity. The scaling properties of our obtained distributions are analyzed with respect to changes in several scaling parameters such as lower magnitude cutoff of earthquakes, the maximum time interval between earthquakes, and the spatial size of the area considered. This scaling behavior can be described in a unified manner by utilizing the multifractal fit. Utilizing the percolation approach the time evolution of clusters of earthquakes is studied with the correlation length defined in terms of the radius of gyration of clusters. This method is applied to the seismicity of California.  相似文献   

The origin of reaction textures in mantle peridotite xenoliths from Sal Island, Cape Verde: the case for “metasomatism” by the host lava   总被引：1，自引：1，他引：1  

Cliff S. J. Shaw  Florian Heidelbach  Donald B. Dingwell 《Contributions to Mineralogy and Petrology》2006,151(6):681-697

Reaction zones around minerals in mantle xenoliths have been reported from many localities worldwide. Interpretations of the origins of these textures fall into two groups: mantle metasomatic reaction or reaction during transport of the xenoliths to the surface. A suite of harzburgitic mantle xenoliths from Sal, Cape Verde show clear evidence of reaction during transport. The reactions resulted in the formation of olivine–clinopyroxene and Si- and alkali-rich glass reaction zones around orthopyroxene and sieve-textured clinopyroxene and sieve textured spinel, both of which are associated with a Si- and alkali-rich glass similar to that in the orthopyroxene reaction zones. Reaction occurred at pressures less than the mantle equilibration pressure and at temperatures close to the liquidus temperature of the host magma. In addition, there is a clear spatial relation of reaction with the host lava: reaction is most intense near the lava/xenolith contact. The residence time of the xenoliths in the host magma, determined from Fe–Mg interdiffusion profiles in olivine, was approximately 4 years. Our results cannot be reconciled with a recent model for the evolution of the mantle below the Cape Verde Archipelago involving mantle metasomatism by kimberlitic melt. We contend that alkali-rich glasses in the Sal xenoliths are not remnants of a kimberlitic melt, but rather they are the result of reaction between the host lava or a similar magma and xenolith minerals, in particular orthopyroxene. The formation of a Si- and alkali-rich glass by host magma–orthopyroxene reaction appears to be a necessary precursor to formation of sieve textured spinel and clinopyroxene.  相似文献   

Facies architecture of a submarine fan channel–levee complex: the Juniper Ridge Conglomerate, Coalinga, California     

Thomas A. Hickson  & Donald R. Lowe† 《Sedimentology》2002,49(2):335-362

The Upper Cretaceous Juniper Ridge Conglomerate (JRC) near Coalinga, California, provides a rare, high-quality exposure of a submarine channel to overbank transition. The facies architecture of the JRC comprises a thick, predominantly mudstone sequence overlain by a channellized conglomerate package. Conglomeratic bounding surfaces truncate successions of interbedded turbiditic sandstones and mudstones both vertically and laterally. Thick-bedded, massive sandstones are interbedded with conglomerates. Facies architecture, palaeocurrent indicators, slump features, sandstone percentages and sandstone bed thickness trends lead to the interpretation that these elements comprise channel and overbank facies. A vertical sequence with conglomerate at the base, followed by thick-bedded sandstone, and capped by interbedded turbiditic sandstone and mudstone form a fining-upward lithofacies association that is interpreted as a single channel-fill/overbank system. Three similar lithofacies associations can be related to autocyclic processes of thalweg migration and submarine fan aggradation or to allocyclically driven changes in sediment calibre.  相似文献   

Rates of Deglaciation during the Last Glaciation and Holocene in the Cordillera Vilcanota-Quelccaya Ice Cap Region, Southeastern Perú     

Bryan G. Mark  Geoffrey O. Seltzer  Donald T. Rodbell  Adam Y. Goodman 《Quaternary Research》2002,57(3):287

Moraine chronology is combined with digital topography to model deglacial rates of paleoglacier volumes in both the Huancané Valley on the west side of the Quelccaya Ice Cap and the Upismayo Valley on the northwest side of the Cordillera Vilcanota. The fastest rates of deglaciation (39×10⁻⁵ to 114×10⁻⁵ km³ yr⁻¹ and 112×10⁻⁵ to 247×10⁻⁵ km³ yr⁻¹ for each valley, respectively) were calculated for the most recent paleoglaciers, corresponding to the last few centuries. These results are consistent with observations in the Venezuelan Andes showing high rates of deglaciation since the Little Ice Age. These rates also fall within the range of 20th century rates of deglaciation measured on the Quelccaya Ice Cap (29×10⁻⁵ to 220×10⁻⁵ km³ yr⁻¹, Brecher and Thompson, 1993; Thompson, 2000). These results imply that rates of deglaciation may fluctuate significantly over time and that high rates of deglaciation may not be exclusive to the late 20th century. Equilibrium line altitude (ELA) depressions for the ice volumes of the last glaciation modeled here were computed as 230 m for the Quelccaya Ice Cap and 170 m for the Cordillera Vilcanota. Maximum ELA depressions are lower than previously published: <500 m for the Cordillera Vilcanota and <400 m for the Quelccaya Ice Cap. These lower values could imply a topographic control over paleoglacier extent.  相似文献   

Thermal expansivities of supercooled haplobasaltic liquids     

Joachim Gottsmann  Donald B Dingwell 《Geochimica et cosmochimica acta》2002,66(12):2231-2238

The thermal expansion of supercooled liquids in the haplobasaltic (anorthite-diopside) system have been determined via methods of container-based dilatometry. The expansivity data obtained in this study agree well with estimates provided by previous dilatometric determinations in the system that have relied on alternative experimental strategies. The data have been combined with high-temperature, superliquidus determinations of melt density to obtain expressions for the volume-temperature (V-T) relationships of liquids in the anorthite-diopside system. The V-T data clearly indicate a nonlinear temperature dependence of volume for all melts investigated. The variation is most striking for diopside, where the coefficient of volume thermal expansion decreases ∼56% from temperatures near the glass transition to superliquidus temperatures. With increasing anorthite content, the degree of variation appears to decrease. An₄₂Di₅₈ exhibits a decrease of 39% of its coefficient of thermal expansion and An₉₈Di₀₂ of 33%, respectively. The expansivities obtained in this study cannot be reproduced by means of published models that are based on linear V-T relationships. They require instead a reanalysis of existing pressure-V-T equations of state models for silicate melts.  相似文献   

Climate change impacts on U.S. Coastal and Marine Ecosystems   总被引：1，自引：0，他引：1  

Donald Scavia  John C. Field  Donald F. Boesch  Robert W. Buddemeier  Virginia Burkett  Daniel R. Cayan  Michael Fogarty  Mark A. Harwell  Robert W. Howarth  Curt Mason  Denise J. Reed  Thomas C. Royer  Asbury H. Sallenger  James G. Titus 《Estuaries and Coasts》2002,25(2):149-164

Increases in concentrations of greenhouse gases projected for the 21st century are expected to lead to increased mean global air and ocean temperatures. The National Assessment of Potential Consequences of Climate Variability and Change (NAST 2001) was based on a series of regional and sector assessments. This paper is a summary of the coastal and marine resources sector review of potential impacts on shorelines, estuaries, coastal wetlands, coral reefs, and ocean margin ecosystems. The assessment considered the impacts of several key drivers of climate change: sea level change; alterations in precipitation patterns and subsequent delivery of freshwater, nutrients, and sediment; increased ocean temperature; alterations in circulation patterns; changes in frequency and intensity of coastal storms; and increased levels of atmospheric CO₂. Increasing rates of sea-level rise and intensity and frequency of coastal storms and hurricanes over the next decades will increase threats to shorelines, wetlands, and coastal development. Estuarine productivity will change in response to alteration in the timing and amount of freshwater, nutrients, and sediment delivery. Higher water temperatures and changes in freshwater delivery will alter estuarine stratification, residence time, and eutrophication. Increased ocean temperatures are expected to increase coral bleaching and higher CO₂ levels may reduce coral calcification, making it more difficult for corals to recover from other disturbances, and inhibiting poleward shifts. Ocean warming is expected to cause poleward shifts in the ranges of many other organisms, including commercial species, and these shifts may have secondary effects on their predators and prey. Although these potential impacts of climate change and variability will vary from system to system, it is important to recognize that they will be superimposed upon, and in many cases intensify, other ecosystem stresses (pollution, harvesting, habitat destruction, invasive species, land and resource use, extreme natural events), which may lead to more significant consequences.  相似文献   

The Permeable City: Toronto's Spatial Shift at the Turn of the Millennium     

Betsy Donald 《The Professional geographer》2002,54(2):190-203

This article presents an analysis of the relationship between urban governance restructuring, and global, national, and local action through a case study of the Toronto city‐region. The Toronto city‐region recently underwent a massive reorganization of its governance structures, functions, and jurisdictional boundaries. This restructuring raises questions about why these changes occurred at this particular juncture in the region's history. Why did the city that had always been known in the academic and political discourse as the “city that works” stop “working”? What global and national forces might have accounted for such a radical restructuring? And what did local action contribute? These questions are explored in both historical and contemporary contexts by drawing on insights from regulation theory, urban regime theory, and an analysis of Canada's changing fiscal federalism. This approach informs the role that institutions — regardless of their origin or territorial scope — play in sustaining a local accumulation system, and how this “local” accumulation grounds a national regulatory mode and regime of accumulation. The approach also explores the relationship between regime and regulation theories in the context of policy formation and institution building. The study concludes that the current policy set is incapable of resolving the region's crisis tendencies. Notwithstanding external forces, the current policy set is not inevitable. Globalization does not predetermine all spatial‐economic outcomes.  相似文献   

Shallow-marine sequences as the building blocks of stratigraphy: insights from numerical modelling     

Joep E. A. Storms  Donald J. P. Swift 《Basin Research》2003,15(3):287-303

Two types of depositional sequences can be defined within the sequence stratigraphic framework: the parasequence and the high‐frequency sequence. Both sequences consist of stacked regressive and transgressive deposits. However, a parasequence forms under conditions of overall sea‐level rise, whereas a high‐frequency sequence forms as the sea level oscillates which results in typical forced regressive deposits during sea‐level fall. Both depositional sequences may develop over comparable temporal (10–100 kyr) and spatial (1–20 km wide and 1–40 m thick) scales. Numerical modelling is used to compare the architecture, preservation potential, internal volumes, bounding surfaces, condensed and expanded sections and facies assemblages of parasequences and high‐frequency sequences. Deposits originating from transgression are less pronounced than their regressive counterparts and consist of either preserved backbarrier deposits or shelf deposits. Shoreface deposits are not preserved during transgression. The second half of the paper evaluates in detail the preservation potential of backbarrier deposits and proposes a mechanism that explains the occurrence of both continuous and discontinuous barrier retreat in terms of varying rates of sea‐level rise and sediment supply. The key to this mechanism is the maximum washover capacity, which plays a part in both barrier shoreline retreat and backbarrier‐lagoonal shoreline retreat. If these two shorelines are not balanced, then the retreat of the coastal system as a whole is discontinuous and in time barrier overstep may take place.  相似文献   

The Significance of Ground Water in Small Watershed Studies   总被引：1，自引：0，他引：1  

Donald O. Rosenberry 《Ground water》2003,41(7):881-882

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